Facile Synthesis of CeO2-LaFeO3 Perovskite Composite and Its Application for 4-(Methylnitrosamino)-1-(3-Pyridyl)-1-Butanone (NNK) Degradation

نویسندگان

  • Kaixuan Wang
  • Helin Niu
  • Jingshuai Chen
  • Jiming Song
  • Changjie Mao
  • Shengyi Zhang
  • Saijing Zheng
  • Baizhan Liu
  • Changle Chen
چکیده

A facile and environmentally friendly surface-ion adsorption method using CeCO₃OH@C as template was demonstrated to synthesize CeO₂-LaFeO₃ perovskite composite material. The obtained composite was characterized by X-ray diffraction (XRD), fourier transform infrared spectra (FT-IR), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), thermo-gravimetric analysis and differential scanning calorimetry (TG-DSC), N₂ adsorption/desorption isotherms and X-ray photoelectron spectra (XPS) measurements. The catalytic degradation of nitrosamine 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK) was tested to evaluate catalytic activity of the CeO₂-LaFeO₃ composite. Much better activity was observed for the CeO₂-LaFeO₃ composite comparing with CeO₂ and LaFeO₃. These results suggested that perovskite composite materials are a promising candidate for the degradation of tobacco-specific nitrosamines (TSNAs).

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عنوان ژورنال:

دوره 9  شماره 

صفحات  -

تاریخ انتشار 2016